Background on Chemical Warfare

 
Chemistry

For those who require chemical data, there are pages that give access to a collection of review articles on chemical agents: Toxicity

Toxicity and Effects of Lethal Chemical Warfare Agents provides summary information and some leading references on the effects of nerve agents and vesicants.

Chemical Weapons and Countermeasures

Powerful chemical agents are a necessary but not sufficient condition for a chemical warfare capability. The chemical agent must be delivered in order to threaten someone, and the threat can be countered. Chemical Weapons and Society

Chemical weapons are a topic of intense interest to all; many people are interested in more than just the chemical behavior and toxicity of these compounds, or how these substances can be disseminated or countered. Aids to Researchers

Certain information is included primarily as an aid to researchers, both professional and amateur. Philosophy (and Warning)

This site attempts to organize information on some of the chemical compounds that have been manufactured for use as chemical warfare (CW) agents. Our goal is to provide detailed scholarship on the chemistry of CW agents that is required to understand their demilitarization and their behavior in the environment. We have included enough other information to provide a necessary background for this effort. We have decided, however, to post no information about the manufacture of these compounds. We do this even though we recognize that this information is unclassified and freely available, and that some reactions used for preparation of CW agents are widely known. We made this decision because we do not wish to give any assistance, no matter how minor, to those who would attempt to manufacture these materials.

To anyone who manages to figure out how these compounds are made and is contemplating trying to make one of them, a few words of warning:
  • These compounds are dangerous. If you actually succeed in making one of them and you do not possess and use the proper protective equipment, it will probably be the last thing you do.
  • The proper protective equipment goes way beyond what you are familiar with from your college chemistry laboratory. For example, most Ph.D. chemists have neither seen nor used the type of protective gear the U.S. military requires for work with nerve agents.
  • Each of the manufacturing schemes for current agents requires at least one (and generally several) compound on the Schedule of Chemicals from the Convention on the Prohibition of the Development, Production, Stockpiling, and Use of Chemical Weapons and on Their Destruction. The Convention requires that all sites which produce, process, or consume significant amounts of scheduled chemicals be declared to the government and the Organisation for the Prohibition of Chemical Weapons.
  • Public Law 105-277, which implements the Convention in the United States, makes it unlawful for any person (except for a Federal agency or a duly authorized person) knowingly to develop, acquire, transfer, stockpile, possess, or use any chemical weapon.
The bottom line is that attempting to prepare CW agents is likely to have unpleasant consequences. Don't try it.